?????? (???, ????? 10 ??.)? ?????????????? ??????? ? ??????????? ????????, ?????????? ?? ??????? 3.1.
? ???????????? ????????? ????????? ?????????? ????????????????????????????? ? ????????????. ???????? ??????? ? ???????????? ? ??????? 1 ??????. ????? ??????? ????????? ??????? ????????? ?????????? ?????? ???? (0.1? HCl), ???????????? ? ??????? 30 ?????. ??????????? ????? ????????????? ??????? ??? ??? ??????????? ?????????????? ??????? ????????? ?????????.
??????? 3.4. ?????? ???????? ?? (EtO) 2 MeSiOSiMe (OEt) 2
???????? m=n [H 2 O]/n [(EtO) 2 MeSiOSiMe (OEt) 2] 0,50,751 (EtO) 2 MeSiOSiMe (OEt) 2? ??. ? - ??, ???? 0,00730,00730,0073 ?????,? .2,062,062,06 ???????. ? - ??, ???? 0,003650,005470,0073 ?????,? .0,060,090,12 ?????, ?? 0,05990,08990,1198
??????
1. ??????? ?????????? ?????? ????????????????????? ? ???????? ??????????????? ??????????????? ???????????????????????.
2. ????????? ?????? ?????????? ????????? ?????? ??????????????? ??????????????? R Si (OR) 3? ????????? ?????????????.
. ?????????? ??? ???????????????? ??????????? ????????????? ? ???????????? ???????? ??? ????????????????????. ???????????, ??? ?????? ?????????? ???? ? ??????? ???????????? ???????????? ?? ??????? ?? ??????? ????????????.
. ????????? ????????????? ??????? ??????????????????? ??????: ???? ????????????????, ??? ????????????????????, ??? ??????????????????, ??? ?????????????????????. ????????, ??? ??????? ???????? ????????? ??????? ?? ?????? ?????????? ????, ???????????? ????????? ?????????? ???? ? ???? ???????.
. ???????????, ??? ? ??? ?????????????? ????? ???? ? ??????????? ???????????????? ???????? ????????????, ?? ???????, ??? ? ??? ?????????????????.
?????? ??????????
1. ????????? ?.?. ?????? ???????????????????? ?????//?., «?????». 1 968, 699?.
2.Cogan H.D., Setterstrom C.A. Liquid Phase Miscibility in the Water-Ethanol-TEOS System//Chem. and Eng. News. 1946, 24, p. +2499
.Avnir D., Kaufman V.R. Alcohol is an unnesessary additive in the silicon alkoxide sol-gel process//J. Non - Crystalline Solids. 1987, 192, pp. 180-182
.Brinker CJ, Keefer KD, Schaefer DW, Ashley CS Sol-Gel Transition in Simple Silicates//J. Non-Crystalline Solids. 1982, 48, pp. 47-64
.Stober W., Fink A., Bohn EJ Controlled growth of monodisperse silica spheres in the micron size range//Colloid and Interface Sci. 1 968, 26, pp. 62-69.
.Assink R.A., Kay B.D. Spinnability of silica sols//J. Non-Crystalline Solids, 1988, 99, p. 359
7. ????????? ?.?. ??????????????????? ??????????//?., «??????», 1955, 166?.
8.Anderson R., Arkles B., Larson C.L. Petrarch systems silanes and silicones//Anal. Chem. 1987. V. 59. P. 2707-2209.
.Klemperer W.G., Mainz V.V., Miliar D.M. Better Ceramics Through Chemistry II//Mat. Res. Soc., Pittsburgh. 1986, p.3
.Klemperer W.G., Mainz V.V., Miliar D.M. Better Ceramics Through Chemistry II//Mat. Res. Soc., Pittsburgh. 1986, p.15
.McNeill KJ, DiCaprio JA, Walsh DA, Pratt. R.F. Kinetics and Mechanism of Hydrolysis of a Silicate Triester, Tris (2- methoxyethoxy) phenylsilane//J.Am. Chem. Soc. 1980, 102, p.1859
12. ?????? ?.?.// ????. ?? ????. 1952 85, c.129.
. ???????? ?.?., ?????????? ?.?., ?????????? ?.?. ???????????? ?????// ???????????: ?????, 1976.
.Keefer K.D. Silicon Based Polymer Science: A Comprehensive Resource//Better Ceramics Through Chemistry II., 1984, pp.15 - 24.
15.Pohl E.R., Osterhpltz F.D. Molecular Characterization of Composite Interfaces//Plenum, New York. 1985, p.157
.Aelion R., Loebel A., Eirich F. Hydrolysis of ethyl silicate//J. Am. Chem. Soc. 1950, 72, pp. 5705-5712
.Pope E.J.A., Mackenzie J.D. Sol-gel processing of silica. II. The role of the catalyst//J. Non-Crystalline Solids. 1986, 87, p. 185
18.Corriu R.J.P., Young J.C. The Chemistry of Organic Silicon Compounds//Wiley, New York. 1989, pp. 1241-1288
. ????????? ?.?. ?????????????????? ????????// ????. ???. ????? 1938.? .8. ? .1255.
20.Corriu RJP, LeClercq D., Vioux A., Pauthe M., Phalippou J. Ultrastructure Processing of Advanced Ceramics//Wiley, New York. 1988, pp. 113-126
.Coltrain B.K., Melpolder S.M., Salva J.M. Ultrastructure Processing of Ceramics, Glasses, and Composites//Wiley, New York. 1 989
.Schmidt H., Kaiser A., ??Rudolph M., Lentz A. Science of Ceramic Chemical Processing//Wiley, New York. 1986, pp. 87-93
.Brinker CJ, Keefer KD, Scha...
