?????????????? ???????
???????????? ??????,?,??- 1?????????? ??????,?,?.?. ( J ,??)???? -?????? 13480-3353 (??.?. OH),
(?? CH3-1),
(? CH3-1),
(?? CH3-2),
(? CH3-2),
(?? CH2),
2878 (? CH2),
(CH),
(C=O),
(?? COC),
1136 (? COC) .1.0 (3?,?.,?? 3-1), 1.16 (3?,?.?? 3-2), 3.96 (2?,?., J =10.53,?? 2), 4.16 (1?,?.,??), 4.91 (1?,?.,??) .131 ([?] 2), 71 (160), 57 (41), 43 (109), 41 (64) .2? 3476-3194 (??.?. NH, OH),
(ac CH3-1),
(c CH3-1),
(ac CH3-2),
(ac CH3-2),
(CH2),
(??),
1684 (? =?) .0,89 (3H,?, CH3-1), 0,95 (3H, c,? H3-2), 3,41 (2H,?, J =10.9, CH2), 3,91 (1H, c, CH), 6.77 (1?,?., NH2), 7.06 (1H, c., OH) 71 (98), 57 (15), 43 (64), 41 (36) .2 b3487-3106 (??.?. NH, OH),
1651 (? =?) .0.91 (3?,?.,?? 3-1), 0.95 (3?,?.,?? 3-2), 2.82 (3?,?., J =4.9, CH 3 NH), 3.46 (2?,??. , J =11.2, ?? 2 ??), 3.95 (1?,?., J =8.93, ?? ??) , 5.18 (2?,??.?.,??), 7.29 (1?,??. NH , J =4.89) 161 (4), 113 (15), 103 (14 ), 89 (100), 71 (34), 58 (39), 43 (44), 41 (30) .43600-3200 (??.?. NH),
(?? 3),
(? =?),
(? =???.???),
(?),
(? lO4-),
1468 (?? N +) 1.04 (3?,?.,?? 3-1), 1.25 (3?,?.,?? 3-2), 2.31 (3?,?.,?? 3 ??), 3.92 (3?,?. , CH3-3), 4.13 (2?,??. J =10.9,?? 2), 5.83 ( 1?,?.,??) 173 (1), 130 (2), 114 (3), 86 (24), 71 (18), 56 (18), 41 (16) .63595-3319 (?? .?. NH),
(? =?),
1726 (? =???.??) 1.20 (3?,?.,?? 3-1), 1.31 (3?,?.,?? 3-2), 2.05 (3? ,?.,?? 3??), 3.30 (3?,?.,?? 3N +), 3.97 (2?,??., J =11.5,?? 2), 5.70 (1?,?.,??), 6.32 (1?,?., NH) - 73582-3339 (??.?. NH, OH),
- (??),
(? =?),
(? =???.????.),
(? =?),
, 1469 (?? + N),
(?)
(? lO4-) 1.08 (3?,?.,?? 3-1), 1.23 (3?,?.,?? 3-2), 2.10 (3?,?.,?? 3? ?), 4.04 (2?,?? . , J =9.16,?? 2), 4.11 (1?,?.,??), 5.36 (1 ?,?.,??), 6.94 (1?,?., 3 -?, 4 -?), 7.07 (1?,? ., J =8.9,?), 7.38 (1?,?.?., J =7.1, J =1.12, 7 -?), 7.59 (1?,?.?., J =7.1, J =1.12, 6 -?), 7.71 (2?,?., J =9.56, 8 -?, 5 -? ), 8.09 (1?,?. J= 8.9,?)
- 103300-3606 (NH),
(??),
1626 (? =?) .6.94 (1?,?.,??), 7.07 (1?,?., J =9.0 ), 7.38 (1?,?.?., J =7.2, J =1.2,? - 9), 7.59 (1?,?.?., J =7.2, J =1.1,? - 8), 7.67 - 7.74 ( 4?,?.,???), 8.10 (1?,?., J =9.0,?) -
??? ?? ???? ????????? ??????? ???????????? ? ??????????? ? ????? ??????????. ???????????? ????????? ?????????? ????? ??????? ???????????? ? ?????????? ??? ????????? ???????? ? ??????? 8?????. ????? ???? ??????????? ?? ?????? 24????,????? ???????? ????????????,?????????????? ?????? ?????????? ????? (??? 2).
????? 2
? ?????????? ??????? ?????????????? ???????????????? ??????????? ????? 2b [49],??????? ?? ???????????? ?????? ??????????????? ?? ??????????? ?????. ?????????? ?????? ????? ?????? ???????????? ? ?????????? ????,??? ?????????? ? ?????????? ??????? ??????...