CLS c: PROGRAMM. BAS FOR OUTPUT AS # 1=8.31 # 1, T, OC raquo ;, INT. SEL. PROC. TO=210 TO 310 STEP 10=TO + 273.15=EXP (9.05 - 63800/(R * Т))=EXP (13 - 83000/(R * Т))=(Kl/(Kl + K2) * 100 # 1, TO, FOTOTO=210 TO 230 STEP 10 # 1, T= raquo ;; TO; ОС =TO + 273.15=28.5=32=Ma * 273.15 * 100000/(22.4 * T * +101325) =My * 273.15 * 100000/(22.4 * T * +101325) b=.1 TO 0.5 STEP.001=1/(Ma/Pa + (b * My/Py) /.21)%=C * 22.4 * T/ T0 # 1, b= raquo ;; b, CAO= raquo ;; CAO, CAO%= raquo ;; CAO% # 1, Xa, proc. raquo ;, GbRIV, mol/ (g * s) raquo ;, GbRPS, mol/(g * s) raquo ;, tRIV, min raquo ;, tRPS, min Xyl=.1 TO 85 STEP 21=Xyl/100=CAO * b=EXPO.05 - 63800/(R * T))=EXP (13 - 83000/(R * T))
К=Kl + K2
КО=Kl +.6 * K2=Kl/К=Xy * Су/(CAO * (.5 * F + 3 * (1 - F)))=Xa * 100=Kl * CAO * (1 - Xa)/(1 + CAO * Xa * F +.6 * CAO * Xa * (1 - F))=K2 * CAO * (1 - Xa)/(1 + CAO * Xa * F +.6 * CAO * Xa * (1 - F))=rl + r2=Kl * К * Xa/(LOG (1/(1 - Xa)) * (K/CAO + КО) - КО * Xa) # 1 , Xa, Xyl, GbRIV=Kl * К * (1 - Xa)/(K + CA0 * Xa + K0)=CA0 * 1/(K1 + K2) ^ 2 * (LOG (1/(1 - Xa)) * ((K1 + K2)/CA0 + (K1 +.6 * K2) - (K1 +.6 * K2) * Xa=(Xa * ((K1 + K2) + CA0 * Xa * (K1 +.6 * K2)))/((K1 + K2) ^ 2 * (1 - Xa)) XylXyl=85 TO 100 STEP 3,75=Xyl/100=CAO * b
Kl=EXP (9.05 - 63800/(R * T))=EXP (13 - 83000/(R * T))
К=Kl + K2
КО=Kl +.6 * K2=Kl/К=Xy * CyO/(CAO * (.5 * F + 3 * (1 - F)=Xa * 100=Kl * CAO * (1 - Xa)/(1 + CAO * Xa * F +.6 * CAO * Xa * (1 - F))=K2 * CAO * (1 - Xa)/(1 + CAO * Xa * F +.6 * CAO * Xa * (1 - F))=r1 + r2=Kl * К * Xa/(LOG (1/(1 - Xa)) * (K/CAO + КО) - КО * Xa)=Kl * К * (1 - Xa)/(K + CA0 * Xa + K0)=CA0 * 1/(K1 + K2) ^ 2 * (LOG (1/(1 - Xa)) * ((K1 + K2)/CA0 + (K1 +.6 * K2) - (K1 +.6 * K2) * Xa=(Xa * ((K1 + K2) + CA0 * Xa * (K1 +.6 * K2)))/((K1 + K2 ) ^ 2 * (1 - Xa)) # 1, Xal, Xyl, GbRIV, GbRPC, tRIV, tRPCXylbTO # 1
END
4. Результати програми
T, 0C INT.SEL.PROC.
210 69.67978
220 67.59289
230 65.52074
240 63.47205
250 61.45447
260 59.47458
270 57.53792
280 55.64904
290 53.81159
300 52.02832
310 50.30124
T=210 0C=.35 CA0=9.340839E - 03 CA0%=37.0177
____________________________________________________________________
| Xa | Xy | GbRIV, mol/(g * s) | Gbrps, mol/(g * s) | tRIV, c | tRPS, c |
========================================== ====================
| 0.027822 | 0.10 | 0.9989E - 05 | 0.5312E - 05 | 0.4528E + 00 | 0.1813E + 00
| 5.870403 | 21.10 | 0.9692E - 05 | 0.4206E - 05 | 0.4672E + 01 | 0.4065E + 02
| 11.712984 | 42.10 | 0.9389E - 05 | 0.3404E - 05 | 0.4775E + 01 | 0.8651E + 02
| 17.555567 | 63.10 | 0.9079E - 05 | 0.2795E - 05 | 0.4866E + 01 | 0.1389E + 03
| 23.398146 | 84.10 | 0.8761E - 05 | 0.2317E - 05 | 0.5047E + 01 | 0.1994E + 03
| 23.648544 | 85.00 | 0.8747E - 05 | 0.7613E - 05 | 0.5269E + 01 | 0.1179E + 03
| 24.691862 | 88.75 | 0.8690E - 05 | 0.7509E - 05 | 0.5459E + 01 | 0.1214E + 03
| 25.735182 | 92.50 | 0.8632E - 05 | 0.7404E - 05 | 0.5550E + 01 | 0.1248E + 03
| 26.778498 | 96.25 | 0.8574E - 05 | 0.7299E - 05 | 0.5643E ??+ 01 | 0.1280E + 03
| 27.821815 | 100.00 | 0.8515E - 05 | 0.7195E - 05 | 0.5837E + 01 | 0.1311E + 03=.36 CA0=9.176964E - 03 CA0%=36.3683
_____________________________________________________________________
| Xa | Xy | GbRIV, mol/(g * s) | Gbrps, mol/(g * s) | tRIV, c | tRPS, c |
+ ========================================= =====================
| 0.028617 | 0.10 | 0.9814E - 05 | 0.5218E - 05 | 0.4980E + 00 | 0.1865E + 00
| 6.038129 | 21.10 | 0.9514E - 05 | 0.4118E - 05 | 0.5188E + 02 | 0.4189E + 02
| 12.047640 | 42.10 | 0.9207E - 05 | 0.3322E - 05 | 0.5223E + 02 | 0.8933E + 02
| 18.057152 | 63.10 | 0.8893E - 05 | 0.2719E - 05 | 0.5306E + 03 | 0.1438E + 03
| 24.066664 | 84.10 | 0.8571E - 05 | 0.2247E - 05 | 0.5405E + 03 | 0.2069E + 03
| 24.324217 | 85.00 | 0.8557E - 05 | 0.7413E - 05 | 0.5527E + 03 | 0.1202E + 03
|...
